The 1H n.m.r. spectra of various steroids and triterpenoids and their hydroxy-derivatives have been studied. It is shown that a consideration of deshielding by hydroxy-groups can provide valuable information on the likely course of intramolecular hydrogen abstraction reactions of alkoxyl radicals.
R. B. Boar, J. Chem. Soc., Perkin Trans. 1, 1975, 1275 DOI: 10.1039/P19750001275
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