The product distribution and the relative rates of reaction of some substituted with palladium(II) chloride in aqueous 1,2-dimethoxyethane are consistent with there being small but significant carbocation character in the transition state of the oxypalladation step.
F. R. S. Clark, R. O. C. Norman and C. B. Thomas, J. Chem. Soc., Perkin Trans. 1, 1975, 1230 DOI: 10.1039/P19750001230
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