Transetherification of sclareol (labd-14-ene-8,13-diol)(1) with triethyl orthoacetate and subsequent rearrangement gave (E)- and (Z)-ethyl 8-hydroxylabd-13-en-15-ylacetate (2) and (3)(R = CO2Et). Products of cyclisation of these esters with tin(IV) chloride in benzene were characterised. Similar reactions with sclareol monoacetate (11) are described and stereochemical implications are discussed.
J. M. Mellor and J. A. M. da Cunha Pinto, J. Chem. Soc., Perkin Trans. 1, 1975, 1009 DOI: 10.1039/P19750001009
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...