The structure (III) of fusicoccin J, a minor glucoside produced by Fusicoccum amygdali, has been determined by its synthesis from fusicoccin (Ia). Feeding experiments have established that fusicoccin J can act as an efficient precursor of fusicoccin. This suggests that the new fusicoccin is a late intermediate on the biosynthetic pathway.
K. D. Barrow, D. H. R. Barton, E. Chain, D. Bageenda-Kasujja and G. Mellows, J. Chem. Soc., Perkin Trans. 1, 1975, 877 DOI: 10.1039/P19750000877
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