Issue 2, 1975

o-Quinonoid compounds. Part VIII. Photodecarbonylation of 1,3-diphenylinden-2-one adducts; 1,5-sigmatropic shifts in sterically stabilised o-quinodimethanes

Abstract

Photodecarbonylation of the 1,3-diphenylinden-2-one-substituted maleimide adducts (9a and b) gave the sterically stabilised o-quinodimethanes (3b and c), which undergo 1,5-sigmatropic shift of the imido-group rather than alkyl migration.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1975, 171-175

o-Quinonoid compounds. Part VIII. Photodecarbonylation of 1,3-diphenylinden-2-one adducts; 1,5-sigmatropic shifts in sterically stabilised o-quinodimethanes

D. W. Jones and G. Kneen, J. Chem. Soc., Perkin Trans. 1, 1975, 171 DOI: 10.1039/P19750000171

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