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This spectroscopic and thermodynamic study of aqueous dimethyl sulphoxide (DMSO) suggests that the properties of the system are dominated by direct component interaction. Maximum inter-action occurs in the region of 0.35 mole fraction (DMSO) and “enhancement of water structure” by added solute is absent, except perhaps at very low concentration, < 0.01 mole fraction. The excess enthalpy HE, is compared with literature values.
M. F. Fox and K. P. Whittingham, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 1407 DOI: 10.1039/F19757101407
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