A novel pulsed method of operating a stirred-flow reactor is described and the appropriate kinetic equations are derived. The technique enables gas kinetic data for pyrolysis reactions to be obtained rapidly and economically; it has been tested by measuring the rate of thermal isomerisation of cyclopropane.
A. C. Baldwin, I. M. T. Davidson and A. V. Howard, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 972 DOI: 10.1039/F19757100972
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