The standard enthalpy of formation of Rh6(CO)16 has been determined as ΔH°f[Rh6(CO)16, c]=–577.9 ± 4 kcal mol–1(–2418 ± 17 kJ mol–1) from measurements of the enthalpy of thermal decomposition by high temperature microcalorimetry. The bond enthalpy contributions (Rh–CO) and (Rh–Rh) are estimated at 39.6 and 27.3 kcal mol–1 respectively.
D. L. S. Brown, J. A. Connor and H. A. Skinner, J. Chem. Soc., Faraday Trans. 1, 1975, 71, 699 DOI: 10.1039/F19757100699
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