Crystal structure of tris(dithiocarbamato)cobalt(III)

Abstract

The crystal structure of the title compound has been determined by direct methods from X-ray diffractometer data and refined by full-matrix least-squares to R 0.050 for 3 448 observed reflections. Crystals are monoclinic, space group P2₁/a, a= 16.300(2), b= 10.056(2), c= 7.095(1)Å, β= 101.00(2)°, Z= 4. Co–S distances range from 2.258(1) to 2.292(1)Å, and C–N 1.316(6) to 1.325(5)Å