The kinetics of halogen exchange in binary mixtures of trimethyltin halides in solution have been investigated by total line-shape analyses of their 1H n.m.r. spectra. The results obtained for solvents of different permittivities allows a distinction to be made between an associative or dissociative mechanism and it is concluded that ionization does play a part in the kinetics.
J. A. Ladd and B. R. Glasberg, J. Chem. Soc., Dalton Trans., 1975, 2378 DOI: 10.1039/DT9750002378
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