Issue 22, 1975

Kinetics and mechanism of oxidation of diaqua[2,2-difluoro-5,6,12,13-tetramethyl-1,3-dioxa-4,7,11,14-tetra-aza-2-boracyclotetradeca-4,6,11,13-tetraene(1–)-NNNN‴]cobalt(II) perchlorate

Abstract

The kinetics and mechanism of irreversible oxidation of the title complex in water by oxygen, have been studied. The process is accelerated by halide ions and by increase in acidity. A comparison is made with oxymyoglobin.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 2329-2332

Kinetics and mechanism of oxidation of diaqua[2,2-difluoro-5,6,12,13-tetramethyl-1,3-dioxa-4,7,11,14-tetra-aza-2-boracyclotetradeca-4,6,11,13-tetraene(1–)-NNNN‴]cobalt(II) perchlorate

R. Dreos, G. Tauzher, G. Costa and M. Green, J. Chem. Soc., Dalton Trans., 1975, 2329 DOI: 10.1039/DT9750002329

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