Valence-band photoelectron spectra of [Fe(CO)2(η-C5H5)X](X = Cl, Br, I, or Me) and [{Fe(CO)(η-C5H5)}4] are reported and compared with the previously published spectra of [Fe(C5H5)2] and Fe(CO)5. Analysis of the spectra indicates that a treatment in terms of the local symmetry of the C5H5 ring can be used to assign the observed bands.
D. A. Symon and T. C. Waddington, J. Chem. Soc., Dalton Trans., 1975, 2140 DOI: 10.1039/DT9750002140
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