Issue 20, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

Kinetics of decomposition of hyperoxovanadium(IV) ions in the presence of vanadium(IV)

Monique Gardès-Albert,   Christiane Ferradini  and  Jacques Pucheault  

Abstract

A study of the kinetic behaviour of [VO(O2)]+ ions in 0.4M-H2SO4 under different conditions has led to a radical mechanism for their decomposition which is catalyzed by [VO]2+ and retarded by [VO2]+. The rate constant for the reaction between [VO]2+ and H2O2(k1) and the ratio of those for the reactions between [VO(O2)]+ and OH (k4) and [VO]2+ and OH (k3) have been determined as 0.97 ± 0.07 l mol–1s–1 and 33 ± 1 : 1 respectively.

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Article information

DOI
https://doi.org/10.1039/DT9750002075
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 2075-2079

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Kinetics of decomposition of hyperoxovanadium(IV) ions in the presence of vanadium(IV)

M. Gardès-Albert, C. Ferradini and J. Pucheault, J. Chem. Soc., Dalton Trans., 1975, 2075 DOI: 10.1039/DT9750002075

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