Issue 19, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

Formation of penta-ammine(dinitrogen)- and cis-tetra-amminehydroxo-nrtrosyl-ruthenium from penta-amminenitrosylruthenium and hydroxide ion

Frank Bottomley,   Enos M.R. Kiremire  and  Steven G. Clarkson  

Abstract

When[Ru(NH3)5(NO)]3+ is set aside in 0.1M aqueous NaOH for 7 d, [Ru(NH3)5(N2)]2+(25%),cis-[Ru(OH)-(NH3)4(NO)]2+(11%), and trans-[Ru(OH)(NH3)4(NO)]2+(8%) are formed. Evidence is presented that the reactions (i) and (ii) are occurring. The [Ru(OH)(NH3)4(NO)]2+ formed is the cis-isomer. [Ru(NH3)5(NO)]3++OH–⇌[Ru(NH2)(NH3)4(NO)]2+(i), [Ru(NH3)5(NO)]3++[Ru(NH2)(NH3)4(NO)]2+→[(H3N)5Ru{N(O)NH2}Ru(NH3)4(NO)]5+→[Ru(NH3)5(N2)]2++[Ru(OH)(NH3)4(NO)]2+(ii)

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9750001909
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 1909-1912

Permissions

Request permissions

Formation of penta-ammine(dinitrogen)- and cis-tetra-amminehydroxo-nrtrosyl-ruthenium from penta-amminenitrosylruthenium and hydroxide ion

F. Bottomley, E. M.R. Kiremire and S. G. Clarkson, J. Chem. Soc., Dalton Trans., 1975, 1909 DOI: 10.1039/DT9750001909

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements