An apparatus for generation of metal vapours and their reactions with potential ligand precursors are described. Co-condensation of titanium atoms with benzene, toluene, or mesitylene gives the compounds [(H6C6)2Ti], [(MeC6H5)2Ti], and [(mes)2Ti], respectively. Symmetrical sandwich structures are proposed for these compounds on the basis of 1H n.m.r., i.r., mass, and photoelectron spectroscopy.
M. T. Anthony, M. L. H. Green and D. Young, J. Chem. Soc., Dalton Trans., 1975, 1419 DOI: 10.1039/DT9750001419
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