Issue 14, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reactions of bis[1,2-bis(diphenylphosphino)ethane](η-ethylene)molybdenum(0) with some electrophilic reagents and carbon dioxide

Takashi Ito  and  Akio Yamamoto  

Abstract

The reactions of [Mo(C2H4)(dppe)2][dppe = 1,2-bis(diphenylphosphino)ethane] with CF3CO2H and organic halides RX (R = Ph. X = Cl, Br, and l; R = PhCH2. X = Cl; R = Me, X = l) have been studied. Reaction with CF3CO2H affords two types of complex. [Mo(O2CCF3)2(dppe)2] and [Mo(O2CCF3)(dppe)2]+(isolated as [BPh4]– salt); that with RX gives [MoX2(dppe)2]. The complex [Mo(C2H4)(dppe)2] reacts with CO2 giving two types of product depending on the reaction conditions: with light irradiation, a CO2 adduct is obtained, whereas with heat cis-[Mo(CO)2(dppe)2] is the main product.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9750001398
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 1398-1401

Permissions

Request permissions

Reactions of bis[1,2-bis(diphenylphosphino)ethane](η-ethylene)molybdenum(0) with some electrophilic reagents and carbon dioxide

T. Ito and A. Yamamoto, J. Chem. Soc., Dalton Trans., 1975, 1398 DOI: 10.1039/DT9750001398

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements