The isolation and characterisation of N2H-bridged complexes formed during hydrazine reduction of cis-[Pt(PR3)2Cl2] are reported. Factors affecting the stability of these new N2H complexes have been studied together with reactivity towards nucleophiles, hydrogen, and carbon monoxide.
M. Keubler, R. Ugo, S. Cenini and F. Conti, J. Chem. Soc., Dalton Trans., 1975, 1081 DOI: 10.1039/DT9750001081
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