Issue 8, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

Mercaptide insertion reactions of an iron–iron bond

Christopher J. Jones  and  Jon A. McCleverty  

Abstract

The reaction between (CF3)2C2S2 and [{Fe(XR)(CO)3}2](XR = SMe, SEt, SPh, or SePh) affords the salts [Fe2(XR)3(CO)6]+[{Fe{(CF3)2C2S2}2}2]–. A reaction sequence is proposed involving oxidation of [{Fe(XR)(CO)3}2] to [{Fe(XR)(CO)3}2]+ followed by formal insertion of RX· into the iron–iron bond to give [Fe2(XR)3(CO)6]+. Thus the compounds [Fe2(XR)3(CO)6]+[PF6]–(XR = SMe or SPh) were prepared from [{Fe(XR)(CO)3}2] using NOPF6 as the oxidising agent.

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Article information

DOI
https://doi.org/10.1039/DT9750000701
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 701-704

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Mercaptide insertion reactions of an iron–iron bond

C. J. Jones and J. A. McCleverty, J. Chem. Soc., Dalton Trans., 1975, 701 DOI: 10.1039/DT9750000701

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