Issue 8, 1975

Crystal and molecular structure of 2-acetylpyridine[9-(2-pyridyl)-4,8-diazadec-8-en-1-amine]nickel(II) diperchlorate

Abstract

Crystals of the title compound (I) are monoclinic, space group P21/c, a= 16.591(10), b= 10203(20), c= 16.164(10)Å, β= 102.65(3)°, Z= 4. The structure was refined by full-matrix least-squares to R 0.076 for 2343 unique reflexions measured by diffractometer. In the cation there is distorted octahedral co-ordination of nickel by the quadridentate ligand and a 2-acetyipyridine molecule in the keto-form. There is evidence for disorder of the perchlorate anions. Ni–N Distances are 2.07–2.09 Å for the quadridentate ligand; for the acetylpyridine, Ni–N 2.138(11), Ni–O 2.124(11), and C[double bond, length half m-dash]O 1.236 (13)Å.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 666-668

Crystal and molecular structure of 2-acetylpyridine[9-(2-pyridyl)-4,8-diazadec-8-en-1-amine]nickel(II) diperchlorate

G. M. Sheldrick and D. A. Stotter, J. Chem. Soc., Dalton Trans., 1975, 666 DOI: 10.1039/DT9750000666

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