Some vinyltrimethylsilanes give high yields of substitution products in aliphatic Friedel–Crafts acylation and the reaction is site-selective, acylation taking place at the carbon atom carrying the trimethylsilyl group.
I. Fleming and A. Pearce, J. Chem. Soc., Chem. Commun., 1975, 633b DOI: 10.1039/C3975000633B
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