Studies of the rates of decomposition of nitramide (NO2NH2) and deuteriated nitramide in H2O and D2O, containing a series of phenolate bases, show that the overall isotope effect for this nitrogen acid passes through a maximum in the region ΔpK=ca. 0, behaviour which is similar to that observed for carbon acids; for catalysis by the nitramide anion the magnitude of the isotope effect is lower than expected.
J. R. Jones and T. G. Rumney, J. Chem. Soc., Chem. Commun., 1975, 995 DOI: 10.1039/C39750000995
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