Issue 24, 1975

Novel photorearrangement of 2,5-dihydroxytriptycene and ionic rearrangement of the photoproduct

Abstract

Irradiation of 2,5-dihydroxytriptycene in methanol with Pyrex-filtered u.v. light gave an epoxyketone which rearranged back to a triptycene-like ketone by reduction with LiAlH4 followed by dehydration over P2O5.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 969-970

Novel photorearrangement of 2,5-dihydroxytriptycene and ionic rearrangement of the photoproduct

H. Iwamura and H. Tukada, J. Chem. Soc., Chem. Commun., 1975, 969 DOI: 10.1039/C39750000969

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