SCHEDULED MAINTENANCE
The formation of the allylic nitrates, (1b) and (2b), in the reactions of both ent-16-kaurene (1a) and ent-15-kaurene (2a) with thallium(III) trinitrate, and a [3,3]-sigmatropic rearrangement between (1b) and (2b), are reported.
M. Ochiai and E. Fujita, J. Chem. Soc., Chem. Commun., 1975, 967 DOI: 10.1039/C39750000967
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