Triamantane has been synthesised from diamantane-1-carboxylic acid, the key step involving multiple rearrangement of a polycyclic olefin in hydrogen in the gas phase on a platinum–silica catalyst.
W. Burns, M. A. McKervey and J. J. Rooney, J. Chem. Soc., Chem. Commun., 1975, 965 DOI: 10.1039/C39750000965
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