The reaction of [1,2,3-(η5-C5H5) CoMe2C2B4H4] with [Fe(CO)5] produced [{(CO)3Fe}2(η5-C5H5) CoMe2C2-B4H4], which is a nine-vertex polyhedral cage system containing the highest ratio of metal to nonmetal cage atoms among known metallocarboranes and the first example of a mixed-metal trimetallocarborane.
W. M. Maxwell and R. N. Grimes, J. Chem. Soc., Chem. Commun., 1975, 943 DOI: 10.1039/C39750000943
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