The quantum yields for geometrical isomerisation and 1,4-cyclomerisation of cis- and trans-penta-1,3-dienes differ for excitation at 228·8 and 253·7 nm; this is explained by a change in the vibrational modes through which the molecules relax on the S1 hypersurface.
P. Vanderlinden and S. Boué, J. Chem. Soc., Chem. Commun., 1975, 932 DOI: 10.1039/C39750000932
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...