C-Chlorocarbene d6 complexes of Cr0, MnI, and RhIII, (I)–(V), have been obtained from [Me2NCCl2]+Cl– and the appropriate transition metal complex precursor, by four procedures (a, a′, a″, or b); alternative reaction pathways (c or d) lead to other species, including the electron-rich cluster compound [Co3(CO)9CNMe2].
A. J. Hartshorn, M. F. Lappert and K. Turner, J. Chem. Soc., Chem. Commun., 1975, 929 DOI: 10.1039/C39750000929
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