1,2,6-Cyclononatriene is shown by 13C n.m.r. to exist in an unsymmetrical twist-boat-chair conformation that can undergo a hindered pseudorotation (barrier height of 12.9 kcal mol–1) to achieve a C2 time-averaged symmetry.
F. A. L. Anet and I. Yavari, J. Chem. Soc., Chem. Commun., 1975, 927 DOI: 10.1039/C39750000927
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