The conjugate bases of tris(ethylenediamine)-cobalt(III) and nitropenta-amminecobalt(III) are characterized in aqueous hydroxide–dimethylsulphoxide mixtures, pKa values being determined using an acidity function derived from the solvent dependence of the rate of base hydrolysis of chloropenta-amminecobalt(III).
D. M. Goodall and M. J. Hardy, J. Chem. Soc., Chem. Commun., 1975, 919 DOI: 10.1039/C39750000919
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