The pKA of hydrido-cobalamin is determined from the E–pH diagram obtained from cyclic voltammetry of vitamin B 12r, adjusting the sweep rate to eliminate the effect of hydrogen evolution and the kinetic influence of the base-on/base-off reaction.
D. Lexa and J. Savéant, J. Chem. Soc., Chem. Commun., 1975, 872 DOI: 10.1039/C39750000872
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