Intense u.v. irradiation causes rearrangement of tetra- and tri-(perfluoroalkyl)ethylenes to less substituted ethylenes including the terminal olefins; migration of allylic fluorine and allylic perfluoroalkyl groups can occur.
A. N. Bell, R. Fields, R. N. Haszeldine and I. Kumadaki, J. Chem. Soc., Chem. Commun., 1975, 866 DOI: 10.1039/C39750000866
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