1-Alkyladamantanes undergo anodic oxidation in dry acetonitrile to give 3-alkyl-1-adamantyl acetamides and anodic fragmentation to give 1-adamantylacetamide; fragmentation is favoured by loss of a tertiary fragment but is not sensitive to temperature change.
G. J. Edwards, S. R. Jones and J. M. Mellor, J. Chem. Soc., Chem. Commun., 1975, 816 DOI: 10.1039/C39750000816
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