The first pentagonal bipyramidal chromium(III) complex has been prepared and characterized, suggesting that seven-co-ordination may not be as rare as previously assumed and may also be the geometry of intermediates in octahedral substitution reactions.
U. Rychlewska, R. C. Palenik, R. W. King and G. J. Palenik, J. Chem. Soc., Chem. Commun., 1975, 799 DOI: 10.1039/C39750000799
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