The rhenium(V) and osmium(VI) nitrido-complexes [ReNX2(PR3)2](X = Cl, L2= 2PMe2-Ph, 2AsPh3, or bipy; X = Br, L2= 2AsPh3 or bipy), react with disulphur dichloride to give the thionitrosyl complexes [ReClX(NS)(PR3)3] and [OsClX2(NS)L2] respectively, whereas an excess of disulphur dichloride with the nitrides [ReNCl2(PR3)3] gives the rhenium(III) derivatives [ReCl3(NS)(PR3)2].
M. W. Bishop, J. Chatt and J. R. Dilworth, J. Chem. Soc., Chem. Commun., 1975, 780 DOI: 10.1039/C39750000780
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