The reaction of carbon monoxide with triphenyl-(phenylimino)phosphorane proceeds smoothly at room temperature in the co-ordination sphere of PdII to give a PdII-phenyl isocyanide complex, which is converted finally into a PdII-carbonyl complex in the presence of a large excess of carbon monoxide.
J. Kiji, A. Matsumura, S. Okazaki, T. Haishi and J. Furukawa, J. Chem. Soc., Chem. Commun., 1975, 751 DOI: 10.1039/C39750000751
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