Issue 18, 1975

The nature of the carbon–phosphorus bond in methylidynephosphine

Abstract

Nuclear magnetic resonance parameters have been determined for solutions of HCP, and a 1J(13CH) value of 211 Hz is rationalized in terms of sp hybridization at carbon, leading to a triple bond description of the CP bond; the appearance potential of the HCP+ or DCP+ ions from the parent molecules (11·4 ± 0·3 eV) is close to a theoretical value.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 744-745

The nature of the carbon–phosphorus bond in methylidynephosphine

S. P. Anderson, H. Goldwhite, D. Ko, A. Letsou and F. Esparza, J. Chem. Soc., Chem. Commun., 1975, 744 DOI: 10.1039/C39750000744

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements