SCHEDULED MAINTENANCE
Electrochemical oxidation of complexes of the type [Ir(CO)XL2](X = monoanionic ligand, L = tertiary phosphine) in 0·1M Bu4NClO4–CH2Cl2 proceeds on Pt-electrodes as a diffusion controlled, irreversible one electron process, indicating that in the redox addition processes atom transferability plays a more important role than the redox properties of the complex.
J. Večernik, J. Mašek and A. A. Vlček, J. Chem. Soc., Chem. Commun., 1975, 736 DOI: 10.1039/C39750000736
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