Issue 16, 1975

Ligand substitution at five-co-ordinate centres. Effect of oxidation state change on mechanism

Abstract

The mechanism of replacement of tri-p-tolylphosphine by tri-n-butyl phosphite in the five-co-ordinate 1,2-dithiolene complex [Co{P(tolyl)3}{S2C2(CF3)2}2]z is associative when z= 0 and dissociative when z=–1.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 688-689

Ligand substitution at five-co-ordinate centres. Effect of oxidation state change on mechanism

D. A. Sweigart, J. Chem. Soc., Chem. Commun., 1975, 688 DOI: 10.1039/C39750000688

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements