Thermal rearrangements of η2- and η4-3-methylene-4-vinyldihdrofuran-2(3H)-one complexes of iron(0) yield isomeric 1,3-diene complexes via regiospecific 1,3-hydrogen shifts; the mechanistic implications with respect to metal-promoted olefin isomerisations are discussed.
M. Green and R. P. Hughes, J. Chem. Soc., Chem. Commun., 1975, 619 DOI: 10.1039/C39750000619
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