[(η-C5H5)(PPri3)PdBr] reacts with magnesium in tetrahydrofuran to give the novel dimeric complex [µ-(C5H5)-µ-BrPd2(PPri3)2], the crystal structure of which shows that the two palladium atoms are bridged by the bromine atom and the C5H5 ring, which has unequal C–C bonds.
A. Ducruix, H. Felkin, C. Pascard and G. K. Turner, J. Chem. Soc., Chem. Commun., 1975, 615 DOI: 10.1039/C39750000615
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