MgO and CaO showed very high activity for the title isomerization compared with ZnO, TiO2 or silica–alumina; the ration of the isomerization activity of penta-1,4-diene to that of but-1-ene was ca. 107 times higher over the alkaline earth metal oxides than over silica–alumina.
K. Morishige, H. Hattori and K. Tanabe, J. Chem. Soc., Chem. Commun., 1975, 559 DOI: 10.1039/C39750000559
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