Issue 13, 1975

The photochemistry of two rigid β,γ-cyclopropyl ketones, exo- and endo-tricyclo[3,2,1,02,4]octan-6-one

Abstract

Photochemical rearrangement of ketones (3) and (9) to bicyclo-octenones (5) and (11), respectively, can be explained by α-cleavage to (12) and (13), followed by stereoelectronically controlled opening to (14) and (15), and then collapse to products.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 509-510

The photochemistry of two rigid β,γ-cyclopropyl ketones, exo- and endo-tricyclo[3,2,1,02,4]octan-6-one

A. B. Smith, L. Brodsky, S. Wolff and W. C. Agosta, J. Chem. Soc., Chem. Commun., 1975, 509 DOI: 10.1039/C39750000509

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