Electro-oxidation of organo-cobalt(III) and -rhodium(III) chelates yields fairly stable species retaining a σ-bonded organic ligand, which behaves as a carbonium ion being readily transferred to nucleophiles.
Ilya. Levitin, A. L. Sigan and M. E. Vol'pin, J. Chem. Soc., Chem. Commun., 1975, 469 DOI: 10.1039/C39750000469
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