MINDO/3 calculations are reported for the thermal rearrangements of bicyclo[2,1,0]pent-2-ene, and of its 1- and 2-methyl derivatives, to cyclopentadienes, and for the interconversion of 1- and 2-methylcyclo-pentadiene; the results suggest that only normal electrocyclic and sigmatropic rearrangements are involved.
M. J. S. Dewar and S. Kirschner, J. Chem. Soc., Chem. Commun., 1975, 461 DOI: 10.1039/C39750000461
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