Issue 11, 1975

Effects of structural changes on chiral selectivity in molecular complexation

Abstract

Seven macrocyclic ethers containing 2,2′-substituted-1,1′-binaphthyl units as chiral barriers connected through different combinations of OCH2CH2OCH2-CH2O, O[CH2]5O, m-C6H4(CH2O)2 and 2,6-C5H3N(CH2O)2(substituted pyridyl) units complex differently with the enantiomers of the hexafluorophosphate salts of racemic methyl phenylglycinate and methyl valinate.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 444-446

Effects of structural changes on chiral selectivity in molecular complexation

G. W. Gokel, J. M. Timko and D. J. Cram, J. Chem. Soc., Chem. Commun., 1975, 444 DOI: 10.1039/C39750000444

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