In the biological pH range marked stereoselectivity is present in the formation of ternary histidinato-copper complexes containing ligands (A) with positively charged, protonated sidechains; there is preferential formation of the complex containing ligands of the same optical hand, e.g. Cu(L-hist)(L-HA).
G. Brookes and L. D. Pettit, J. Chem. Soc., Chem. Commun., 1975, 385 DOI: 10.1039/C39750000385
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