Thiourea reacts with N-methyl-N-nitrosoaniline without the intermediacy of a free nitrosating agent, to form an S-nitroso-compound; thiourea shows comparable nucleophilic reactivity to iodide ion in this reaction.
D. L. H. Williams, J. Chem. Soc., Chem. Commun., 1975, 375 DOI: 10.1039/C39750000375
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