Issue 9, 1975

A new carbonyl bridging mode: X-ray structure and infrared spectrum of the metal carbonyl derivative [Mn2(CO)5(Ph2PCH2PPh2)2]

Abstract

The i.r. spectrum of the dimeric manganese(0) carbonyl complex [Mn2(CO)5(Ph2PCH2PPh2)2] exhibits an unusually low carbonyl stretching frequency which a crystal structure determination has revealed to be caused by a carbonyl ligand bonded in a novel bridging manner.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 363-364

A new carbonyl bridging mode: X-ray structure and infrared spectrum of the metal carbonyl derivative [Mn2(CO)5(Ph2PCH2PPh2)2]

R. Colton, C. J. Commons and B. F. Hoskins, J. Chem. Soc., Chem. Commun., 1975, 363 DOI: 10.1039/C39750000363

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