Issue 9, 1975

General synthesis of optically pure chiral iron primary alkyls via a metal-activated alkylation reagent

Abstract

Preparation of the optically pure alkylation reagent (3) and its reaction with Grignard and alkyl-lithium reagents provides a general route to iron alkyls whose enantiomeric purity may be shown by the n.m.r. spectra of their SO2 insertion products.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 336-337

General synthesis of optically pure chiral iron primary alkyls via a metal-activated alkylation reagent

T. C. Flood, F. J. DiSanti and D. L. Miles, J. Chem. Soc., Chem. Commun., 1975, 336 DOI: 10.1039/C39750000336

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