Polarographic studies on CuII-1,4,7,10-tetra-azacyclododecane (cyclen) complexation have shown that the thermodynamic and kinetic macrocyclic effect is evident despite the unfavourable steric constraints, and that the increased stability constant of CuII-cyclen compared to CuII-trien is accounted for solely by the entropy term.
M. Kodama and E. Kimura, J. Chem. Soc., Chem. Commun., 1975, 326 DOI: 10.1039/C39750000326
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